I always hold a rag over the key as I do that job. Another advantage of plastic pipes is you don't have to nearly so much. There is a small section of copper in my system. The gas is caused by an electro chemical reaction between the copper pipes and the steel rads. As well as the gas that makes the black sludge and eventually holes in the rads. I think it's hydrogen and copper oxide but I'd need to look that up to be sure.